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Concentrations of perfluorobutanoic acid (PFBA) were much higher than other PFCAs, suggesting PFBA loading on the Devon Ice Cap is influenced by additional sources, such as the oxidation of heat transfer fluids.

All PFCA fluxes increased with time, while PFSA fluxes generally decreased with time.

Snow was analyzed for perfluoroalkyl acids (PFAAs), including perfluoroalkyl carboxylic acids (PFCAs) and perfluoroalkyl sulfonic acids (PFSAs), as well as perfluorooctane sulfonamide (FOSA).

PFAAs were detected in all samples dated from 1993 to 2007. Flux ratios of even–odd PFCA homologues were mostly between 0.5 and 2, corresponding to molar ratios expected from atmospheric oxidation of fluorotelomer compounds.

Manufacturers of specialty chemicals don't seek out “me-too” analytical technologies.


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